Just what Jonathan says but to make it clearer look at the transformer output current ratings for these two transformers.

Both are 625Va but first is 2x25V second is 2x50v.

Standard Range Toroidal Transformers: CM0625225: 625VA 230v to 2x25v

Standard Range Toroidal Transformers: CM0625250: 625VA 230v to 2x50v

If you wired the 2x25V in parallel not series you'd still have 25V but @ 24A So obviously 2x50V in paralle is 50V @12A (6A x 2)